Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II)
The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-aminopyrimidine, [Zn(NO3)(2)(C4H5N3)(2)-(H2O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry abou...
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| Main Authors: | , |
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| Format: | Article |
| Published: |
International Union of Crystallography
2010
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| Subjects: | |
| Online Access: | http://eprints.um.edu.my/12192/ http://journals.iucr.org/e/issues/2010/10/00/jh2204/jh2204bdy.html |
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| Summary: | The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-aminopyrimidine, [Zn(NO3)(2)(C4H5N3)(2)-(H2O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry about the Zn(II) atom is a distorted octahedron. Intramolecular N-H center dot center dot center dot O hydrogen bonds occur. In the crystal, adjacent adduct molecules are linked by O- H center dot center dot center dot O, O-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds into a layer motif parallel to ( 001). |
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