Tribenzylbis(triphenylarsine oxide-kappa O)tin(IV) tetraphenylborate
The crystal structure of the title salt, [Sn(C7H7)(3)(C18H15AsO)(2)][B(C6H5)(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C3SnO2 trigonal-bipyramidal geometry [summation of C-Sn-C angles 360.0 (3)degrees and O-Sn-O angle 173.1 (1)d...
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my.um.eprints.119952019-01-31T04:31:17Z http://eprints.um.edu.my/11995/ Tribenzylbis(triphenylarsine oxide-kappa O)tin(IV) tetraphenylborate Keng, T.C. Lo, K.M. Ng, S.W. Q Science (General) The crystal structure of the title salt, [Sn(C7H7)(3)(C18H15AsO)(2)][B(C6H5)(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C3SnO2 trigonal-bipyramidal geometry [summation of C-Sn-C angles 360.0 (3)degrees and O-Sn-O angle 173.1 (1)degrees]. The structure contains voids of 113 (19) angstrom(3), but no solvent molecule could reasonably be located there. International Union of Crystallography 2010 Article PeerReviewed Keng, T.C. and Lo, K.M. and Ng, S.W. (2010) Tribenzylbis(triphenylarsine oxide-kappa O)tin(IV) tetraphenylborate. Acta Crystallographica Section E: Structure Reports Online, 66 (11). M1372-U352. ISSN 1600-5368 |
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Q Science (General) Keng, T.C. Lo, K.M. Ng, S.W. Tribenzylbis(triphenylarsine oxide-kappa O)tin(IV) tetraphenylborate |
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The crystal structure of the title salt, [Sn(C7H7)(3)(C18H15AsO)(2)][B(C6H5)(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C3SnO2 trigonal-bipyramidal geometry [summation of C-Sn-C angles 360.0 (3)degrees and O-Sn-O angle 173.1 (1)degrees]. The structure contains voids of 113 (19) angstrom(3), but no solvent molecule could reasonably be located there. |
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Article |
author |
Keng, T.C. Lo, K.M. Ng, S.W. |
author_facet |
Keng, T.C. Lo, K.M. Ng, S.W. |
author_sort |
Keng, T.C. |
title |
Tribenzylbis(triphenylarsine oxide-kappa O)tin(IV) tetraphenylborate |
title_short |
Tribenzylbis(triphenylarsine oxide-kappa O)tin(IV) tetraphenylborate |
title_full |
Tribenzylbis(triphenylarsine oxide-kappa O)tin(IV) tetraphenylborate |
title_fullStr |
Tribenzylbis(triphenylarsine oxide-kappa O)tin(IV) tetraphenylborate |
title_full_unstemmed |
Tribenzylbis(triphenylarsine oxide-kappa O)tin(IV) tetraphenylborate |
title_sort |
tribenzylbis(triphenylarsine oxide-kappa o)tin(iv) tetraphenylborate |
publisher |
International Union of Crystallography |
publishDate |
2010 |
url |
http://eprints.um.edu.my/11995/ |
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1643689192423686144 |
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13.15806 |