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Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate.

In the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The Pd(II) ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-pl...

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Main Authors: Khaledi, H., Mohd A, H.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
QD Chemistry
R Medicine
Online Access:http://eprints.um.edu.my/1197/
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050367/
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spelling my.um.eprints.11972019-01-31T02:20:20Z http://eprints.um.edu.my/1197/ Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate. Khaledi, H. Mohd A, H. QD Chemistry R Medicine In the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The Pd(II) ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-planar geometry. In the crystal, the indolic NH groups are bonded to the dimethyl-formamide (DMF) solvent mol-ecules via an N-H⋯O inter-action. In addition, C-H⋯S inter-actions are observed. International Union of Crystallography 2010 Article PeerReviewed Khaledi, H. and Mohd A, H. (2010) Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate. Acta Crystallographica Section E: Structure Reports Online, 67 (Pt 1). m84. ISSN 1600-5368 http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050367/ 21522600
institution Universiti Malaya
building UM Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Malaya
content_source UM Research Repository
url_provider http://eprints.um.edu.my/
topic QD Chemistry
R Medicine
spellingShingle QD Chemistry
R Medicine
Khaledi, H.
Mohd A, H.
Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate.
description In the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The Pd(II) ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-planar geometry. In the crystal, the indolic NH groups are bonded to the dimethyl-formamide (DMF) solvent mol-ecules via an N-H⋯O inter-action. In addition, C-H⋯S inter-actions are observed.
format Article
author Khaledi, H.
Mohd A, H.
author_facet Khaledi, H.
Mohd A, H.
author_sort Khaledi, H.
title Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate.
title_short Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate.
title_full Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate.
title_fullStr Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate.
title_full_unstemmed Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate.
title_sort bis{benzyl 3-[(1h-indol-3-yl)methyl-idene]dithio-carbazato-κn,s}palladium(ii) n,n-dimethyl-formamide disolvate.
publisher International Union of Crystallography
publishDate 2010
url http://eprints.um.edu.my/1197/
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050367/
_version_ 1643686688065585152
score 13.160551

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