Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction
Four metal complexes, namely [Cu(2)(ttzCOO)(2)(H(2)O)(4)]center dot 4H(2)O (1), [Zn(2)(ttzCOO)(2)(H(2)O)6]center dot 2H(2)O (2), [Pb(ttzCOO)(H(2)O)(2)](n) (3), and {[Cd(ttzCOO)(H(2)O)]center dot 1/2H(2)O}(n) (4), where ttzCOO(2-) = tetrazole-5-carboxylate dianion, have been prepared by the reaction...
Saved in:
Main Authors: | , , , , , |
---|---|
Format: | Article |
Published: |
Verlag Z Naturforsch
2010
|
Subjects: | |
Online Access: | http://eprints.um.edu.my/11677/ |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
id |
my.um.eprints.11677 |
---|---|
record_format |
eprints |
spelling |
my.um.eprints.116772017-05-22T06:40:59Z http://eprints.um.edu.my/11677/ Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction Kou, Jun-Feng Su, M. Zhang, Yu-Hong Huang, Zhan-Dong Ng, S.W. Yang, G. Q Science (General) Four metal complexes, namely [Cu(2)(ttzCOO)(2)(H(2)O)(4)]center dot 4H(2)O (1), [Zn(2)(ttzCOO)(2)(H(2)O)6]center dot 2H(2)O (2), [Pb(ttzCOO)(H(2)O)(2)](n) (3), and {[Cd(ttzCOO)(H(2)O)]center dot 1/2H(2)O}(n) (4), where ttzCOO(2-) = tetrazole-5-carboxylate dianion, have been prepared by the reaction of the sodium salt of 1H-tetrazole-5-carboxylic acid ethyl ester in aqueous methanolic solution at room temperature with CuCl(2), Znl(2), Pb(NO(3))(2), or Cd(NO(3))(2), respectively. The compounds were characterized by elemental analysis, IR spectroscopy, TG-DSC analysis and single-crystal X-ray diffraction. While 1 and 2 are structurally similar dinuclear complexes, 3 and 4 exhibit a ID chain structure and a 3D polymeric framework, respectively. Verlag Z Naturforsch 2010 Article PeerReviewed Kou, Jun-Feng and Su, M. and Zhang, Yu-Hong and Huang, Zhan-Dong and Ng, S.W. and Yang, G. (2010) Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction. Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences, 65 (12). pp. 1467-1471. |
institution |
Universiti Malaya |
building |
UM Library |
collection |
Institutional Repository |
continent |
Asia |
country |
Malaysia |
content_provider |
Universiti Malaya |
content_source |
UM Research Repository |
url_provider |
http://eprints.um.edu.my/ |
topic |
Q Science (General) |
spellingShingle |
Q Science (General) Kou, Jun-Feng Su, M. Zhang, Yu-Hong Huang, Zhan-Dong Ng, S.W. Yang, G. Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
description |
Four metal complexes, namely [Cu(2)(ttzCOO)(2)(H(2)O)(4)]center dot 4H(2)O (1), [Zn(2)(ttzCOO)(2)(H(2)O)6]center dot 2H(2)O (2), [Pb(ttzCOO)(H(2)O)(2)](n) (3), and {[Cd(ttzCOO)(H(2)O)]center dot 1/2H(2)O}(n) (4), where ttzCOO(2-) = tetrazole-5-carboxylate dianion, have been prepared by the reaction of the sodium salt of 1H-tetrazole-5-carboxylic acid ethyl ester in aqueous methanolic solution at room temperature with CuCl(2), Znl(2), Pb(NO(3))(2), or Cd(NO(3))(2), respectively. The compounds were characterized by elemental analysis, IR spectroscopy, TG-DSC analysis and single-crystal X-ray diffraction. While 1 and 2 are structurally similar dinuclear complexes, 3 and 4 exhibit a ID chain structure and a 3D polymeric framework, respectively. |
format |
Article |
author |
Kou, Jun-Feng Su, M. Zhang, Yu-Hong Huang, Zhan-Dong Ng, S.W. Yang, G. |
author_facet |
Kou, Jun-Feng Su, M. Zhang, Yu-Hong Huang, Zhan-Dong Ng, S.W. Yang, G. |
author_sort |
Kou, Jun-Feng |
title |
Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
title_short |
Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
title_full |
Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
title_fullStr |
Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
title_full_unstemmed |
Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
title_sort |
synthesis and crystal structures of copper(ii), zinc(ii), lead(ii) and cadmium(ii) tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
publisher |
Verlag Z Naturforsch |
publishDate |
2010 |
url |
http://eprints.um.edu.my/11677/ |
_version_ |
1643689113711280128 |
score |
13.18916 |