Cover Image

3-(2-Hydroxyethyl)-3-methyl-1-(4-methylbenzoyl)thiourea

The title thio­urea derivative, C12H16N2O2S, has a twisted conformation with the dihedral angle between the NC(=S)N and O=CC6 planes being 35.45 (5)°. The observed conformation allows for an intra­molecular N-H...O hydrogen bond. In the mol­ecular packing, supra­molecular aggregation is based on hy­...

Full description

Saved in:
Bibliographic Details
Main Authors: Nazzatush Shimar Jamaludin,, Siti Nadiah Abdul Halim,, Tiekink, Edward R. T. *
Format: Article
Language:English
Published: International Union of Crystallography 2016
Subjects:
QD Chemistry
Online Access:http://eprints.sunway.edu.my/663/1/IUCrData%202016%201%20x152457.pdf
http://eprints.sunway.edu.my/663/
http://dx.doi.org/10.1107/S2414314615024578
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The title thio­urea derivative, C12H16N2O2S, has a twisted conformation with the dihedral angle between the NC(=S)N and O=CC6 planes being 35.45 (5)°. The observed conformation allows for an intra­molecular N-H...O hydrogen bond. In the mol­ecular packing, supra­molecular aggregation is based on hy­droxy-O-H...O(carbon­yl) hydrogen bonding and leads to supra­molecular helical chains along the a axis; chains are reinforced by N-methyl­ene-C-H...S and N-methyl-C-H...[pi](arene) inter­actions. Supra­molecular layers in the ab plane are formed as a result of tolyl-methyl-C-H...[pi](arene) inter­actions.

Similar Items