[μ2-Bis(diphenylphosphanyl)hexane]bis[undecacarbonyl-triangulo-triruthenium(3 Ru—Ru)] hexane monosolvate: crystal structure and Hirshfeld surface analysis

• Main Authors: Omar Shawkataly,, Siti Syaida Sirat,, Jotani, Mukesh M., Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: International Union of Crystallography 2017
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/628/1/Acta%20Cryst.%20%282017%29.%20E73%2C%201652.pdf; http://eprints.sunway.edu.my/628/; http://dx.doi.org/10.1107/S2056989017014517

In the title cluster complex hexane solvate, [Ru6(C30H32P2)(CO)22]·C6H14, two Ru3(CO)11 fragments are linked by a Ph2P(CH2)6PPh2 bridge with the P atoms equatorially disposed with respect to the Ru3 triangle in each case; the hexane solvent mol­ecule is statistically disordered. The Ru...Ru distance...