Exploring the crystallization landscape of cadmium bis(N-hydroxyethyl, N-isopropyldithiocarbamate), Cd[S2CN(iPr)CH2CH2OH]2

• Main Authors: Tan, Yee Seng *, Siti Nadiah Abdul Halim,, Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: De Gruyter 2016
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/617/1/ZKrist.%20231%202016%20113_Deposited.pdf; http://eprints.sunway.edu.my/617/; http://dx.doi.org/10.1515/zkri-2015-1889

Crystallization of Cd[S2CN(iPr)CH2CH2OH]2 from ethanol yields the coordination polymer [{Cd[S2CN(iPr) CH2CH2OH]2}·EtOH]∞ (1) within 3 h. When the solution is allowed to stand for another hour, the needles begin to dissolve and prisms emerge of the supramolecular isomer (SI), binuclear {Cd[S2CN(...