Structural and Hirshfeld surface analysis of thallium(I) and indium(III) complexes of a soft scorpionate ligand

• Main Authors: Fujisawa, Kiyoshi, Kuboniwa, Ayaka, Tan, Sang Loon *, Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: MDPI 2023
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/2190/1/crystals%202023%2013%20745.pdf; http://eprints.sunway.edu.my/2190/; https://www.mdpi.com/2073-4352/13/5/745

Two complexes containing a soft sulfur-substituted tris(pyrazolyl)hydroborate ligand, namely [TlI(TmtBu)]2∙2H2O and [InIII(TmtBu)2](InCl4), where TmtBu is the tris(3-tert-butyl-2-sulfanylidene-1H-imidazol-1-yl)hydroborate anion, have been characterized. The {TlS}2 core of the former has the shape of...