Unusual {⋯HNC2O⋯HCnO}, n = 1 or 2, synthons predominate in the molecular packing of one-dimensional coordination polymers, {Cd[S2P(OR)2]2(3LH2)}n, for R = Me and Et, but are precluded when R = i-Pr; 3LH2 = N,N′-bis(3-pyridylmethyl)oxalamide

• Main Authors: Tan, Yee Seng*, Yeo, Chien Ing*, Kwong, Huey Chong*, Tiekink, Edward R. T.*
• Format: Article
• Language: English
• Published: Royal Society of Chemistry 2022
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/2014/1/Unusual%20HNC2O.pdf; http://eprints.sunway.edu.my/2014/; http://doi.org/10.1039/d2ce00208f

Linear, one-dimensional coordination polymers, {Cd[S2P(OR)2]2(3LH2)}n, for R = Me (1), Et(2) and i-Pr(3) have been fully characterised by a variety of physiochemical, spectroscopic, crystallographic and computational techniques. Two-dimensional layers are apparent in the crystals of 1 and 2, being m...