Bis{N′-[3-(4-nitrophenyl)-1-phenylprop-2-en-1-ylidene]-N-phenylcarbamimidothioato}zinc(II): crystal structure, Hirshfeld surface analysis and computational study

• Main Authors: Tan, Ming Yueh, Kwong, Huey Chong, Crouse, Karen A., Ravoof, Thahira B. S., Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: International Union of Crystallography 2021
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/1831/1/Tiekink%20acta%20cryst%202021%2077.8.%20839.pdf; http://eprints.sunway.edu.my/1831/; http://doi.org/10.1107/S2056989021007398

The title zinc bis­(thio­semicarbazone) complex, [Zn(C22H17N4O2S)2], comprises two N,S-donor anions, leading to a distorted tetra­hedral N2S2 donor set. The resultant five-membered chelate rings are nearly planar and form a dihedral angle of 73.28 (3)°. The configurations about the endocyclic- and e...