Crystal structure analysis and supramolecular association in ethyl N-[amino(iminio)methyl]carbamate dichloride hemi-hydrate

• Main Authors: Bamigboye, C, Abbo, H. S., Kwong, Huey Chong, Tan, Sang Loon *, Tiekink, Edward R. T. *, Kamounah, F. S., Titinchi, S. J. J.
• Format: Article
• Language: English
• Published: Oldenbough Verlag 2021
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/1830/1/Tiekink%20Crystal%20Structure%20acc_z%20kristallogr%202021%20236%20187.pdf; http://eprints.sunway.edu.my/1830/; http://doi.org/10.1515/zkri-2021-2024

X-ray crystallography on [EtOC(=O)N(H)C(=N+H2)NH2]Cl·½H2O (1) shows the asymmetric unit to comprise two independent cations, two chloride anions and crystal water. The main conformational difference between the cations is seen in the relative orientation of the ethyl groups; geometry-optimisation co...