[(Z)-N-(3-Fluorophenyl)-O-methylthiocarbamato-κS](triphenylphosphane-κP)gold(I): crystal structure, Hirshfeld surface analysis and computational study

• Main Authors: Yeo, Chien Ing *, Tan, Sang Loon *, Kwong, Huey Chong *, Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: International Union of Crystallography 2020
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/1330/1/Tiekink%20ActaCryst%202020%20E76%201284.pdf; http://eprints.sunway.edu.my/1330/; http://doi.org/10.1107/S2056989020009469

The title phosphanegold(I) thiolate, C26H22AuFNOPS or [Au(C8H7FNOS)(C18H15P)], has the AuI centre coordinated by phosphane-P [2.2494 (8) A ˚ ] and thiolate-S [2.3007 (8) A ˚ ] atoms to define a close to linear geometry [P—Au—S = 176.10 (3)⁰]. The thiolate ligand is orientated so that the methoxy-O at...