(N,N′-Diisopropyldithiocarbamato)triphenyltin(IV): crystal structure, Hirshfeld surface analysis and computational study

• Main Authors: Farah N. H.,, Normah Awang,, Nurul Farahana Kamaludin,, Jotani, Mukesh M., Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: International Union of Crystallography 2019
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/1103/1/Tiekink%20N%20N%20Diisopropyldithiocarbamato%20Acta%20Cryst.%20%282019%29%20E75%201479.pdf; http://eprints.sunway.edu.my/1103/; http://doi.org/10.1107/S2056989019012490

The crystal and molecular structures of the title triorganotin dithiocarbamate, [Sn(C6H5)3(C7H14NS2)], are described. The molecular geometry about the metal atom is highly distorted being based on a C3S tetrahedron as the dithiocarbamate ligand is asymmetrically chelating to the tin centre. The clo...