Steric control of supramolecular association in structures of Zn(S2COR)2 with N,N′-bis(pyridin-4-ylmethyl)oxalamide

• Main Authors: Tan, Yee Seng *, Chu, Hao Zhe *, Jotani, Mukesh M., Tiekink, Edward R. T. *
• Format: Article
• Language: English
• Published: Oldenbourg Wissenschaftsverlag 2019
• Subjects: QD Chemistry
• Online Access: http://eprints.sunway.edu.my/1001/1/Tieink%20Steric%20%20control%20Z%20Kristallogr%202019%20234%20165%20175_ACCEPTED.pdf; http://eprints.sunway.edu.my/1001/; http://doi.org/10.1515/zkri-2018-2120

The crystal and molecular structures of the one-dimensional coordination polymer [Zn(S2COEt)2(4LH2)]n (1) and binuclear [Zn(S2COCy)2]2(4LH2) (2) are described, where 4LH2 is N,N'-bis(pyridin4-ylmethyl)ethanediamide. In 1, the Zn(S2COEt)2 entities are linked by bidentate bridging 4 LH2 ligands...