Tuning the accessibility and activity of Au25(SR)18 nanocluster catalysts through ligand engineering

In this work, the effects of thiolate ligands (-SR, e.g., chain length and functional moiety) on the accessibility and catalytic activity of thiolate-protected gold nanoclusters (e.g., Au25(SR)18) for 4-nitrophenol hydrogenation is reported. The data suggest that Au25(SR)18 bearing a shorter alkyl...

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Bibliographic Details
Main Authors: Li, Jingguo, Nasaruddin, Ricca Rahman, Feng, Yan, Yang, Jun, Yan, Ning, Xie, Jianping
Format: Article
Language:English
English
Published: WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 2016
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Online Access:http://irep.iium.edu.my/66300/1/2016%20-%20tuning%20cat%20phd%20-%20chem%20eur%20j.pdf
http://irep.iium.edu.my/66300/2/2016%20-%20tuning%20cat%20phd%20-%20chem%20eur%20j%20-%20SD.pdf
http://irep.iium.edu.my/66300/
https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201603247
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