Crystal structure of benzyltriphenylphosphonium chloride monohydrate
The title compound, Ph3(PhCH2)P+ Cl-·H2O, was obtained unintentionally as the product of an attempted synthesis of a silver dithiocarbamate complex using benzyltriphenyl- phosphonium as the counter-ion. The asymmetric unit consists of a phosphonium cation and a chloride anion, and a water molecule o...
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International Union of Crystallography
2015
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الوصول للمادة أونلاين: | http://irep.iium.edu.my/43139/1/Acta_E71_o410-o411.pdf http://irep.iium.edu.my/43139/4/43139_Crystal%20structure%20of%20benzyltriphenylphosphonium_SCOPUS.pdf http://irep.iium.edu.my/43139/5/43139_Crystal%20structure%20of%20benzyltriphenylphosphonium_WOS.pdf http://irep.iium.edu.my/43139/ http://scripts.iucr.org/cgi-bin/paper?su5134 |
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my.iium.irep.431392017-04-10T03:15:33Z http://irep.iium.edu.my/43139/ Crystal structure of benzyltriphenylphosphonium chloride monohydrate Ahmad, Jimmy Abdul Halim, Siti Nadiah How, Fiona Ni Foong QD Chemistry The title compound, Ph3(PhCH2)P+ Cl-·H2O, was obtained unintentionally as the product of an attempted synthesis of a silver dithiocarbamate complex using benzyltriphenyl- phosphonium as the counter-ion. The asymmetric unit consists of a phosphonium cation and a chloride anion, and a water molecule of crystallization. In the crystal, the chloride ion is linked to the water molecule by an O—H·· ·Cl hydrogen bond. The three units are further linked via C—H·· ·Cl and C— H·· ·O hydrogen bonds and C—H··· JT interactions, forming a three-dimensional structure. International Union of Crystallography 2015 Article REM application/pdf en http://irep.iium.edu.my/43139/1/Acta_E71_o410-o411.pdf application/pdf en http://irep.iium.edu.my/43139/4/43139_Crystal%20structure%20of%20benzyltriphenylphosphonium_SCOPUS.pdf application/pdf en http://irep.iium.edu.my/43139/5/43139_Crystal%20structure%20of%20benzyltriphenylphosphonium_WOS.pdf Ahmad, Jimmy and Abdul Halim, Siti Nadiah and How, Fiona Ni Foong (2015) Crystal structure of benzyltriphenylphosphonium chloride monohydrate. Acta Crystallographica Section E Structure Reports Online, 71. o410-o411. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?su5134 10.1107/S2056989015009159 |
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QD Chemistry Ahmad, Jimmy Abdul Halim, Siti Nadiah How, Fiona Ni Foong Crystal structure of benzyltriphenylphosphonium chloride monohydrate |
description |
The title compound, Ph3(PhCH2)P+ Cl-·H2O, was obtained unintentionally as the product of an attempted synthesis of a silver dithiocarbamate complex using benzyltriphenyl- phosphonium as the counter-ion. The asymmetric unit consists of a phosphonium cation and a chloride anion, and a water molecule of crystallization. In the crystal, the chloride ion is linked to the water molecule by an O—H·· ·Cl hydrogen bond. The three units are further linked via C—H·· ·Cl and C— H·· ·O hydrogen bonds and C—H··· JT interactions, forming a three-dimensional structure. |
format |
Article |
author |
Ahmad, Jimmy Abdul Halim, Siti Nadiah How, Fiona Ni Foong |
author_facet |
Ahmad, Jimmy Abdul Halim, Siti Nadiah How, Fiona Ni Foong |
author_sort |
Ahmad, Jimmy |
title |
Crystal structure of benzyltriphenylphosphonium chloride
monohydrate |
title_short |
Crystal structure of benzyltriphenylphosphonium chloride
monohydrate |
title_full |
Crystal structure of benzyltriphenylphosphonium chloride
monohydrate |
title_fullStr |
Crystal structure of benzyltriphenylphosphonium chloride
monohydrate |
title_full_unstemmed |
Crystal structure of benzyltriphenylphosphonium chloride
monohydrate |
title_sort |
crystal structure of benzyltriphenylphosphonium chloride
monohydrate |
publisher |
International Union of Crystallography |
publishDate |
2015 |
url |
http://irep.iium.edu.my/43139/1/Acta_E71_o410-o411.pdf http://irep.iium.edu.my/43139/4/43139_Crystal%20structure%20of%20benzyltriphenylphosphonium_SCOPUS.pdf http://irep.iium.edu.my/43139/5/43139_Crystal%20structure%20of%20benzyltriphenylphosphonium_WOS.pdf http://irep.iium.edu.my/43139/ http://scripts.iucr.org/cgi-bin/paper?su5134 |
_version_ |
1643612329412132864 |
score |
13.149126 |