Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran
The photolysis of 1-octene and molybdenum hexacarbonyl in tetrahydrofuran results in isomerization of the olefin. When the concentration of molybdenum hexacarbonyl is greater than 0.05M less than 1 mole of the isomerized olefin is producedfor each mole of molybdenum hexacarbonyl. The efficiency of t...
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1977
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my.iium.irep.302352019-09-05T02:16:01Z http://irep.iium.edu.my/30235/ Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran Card, Roger J. Omar, Muhammad Nor QD Chemistry The photolysis of 1-octene and molybdenum hexacarbonyl in tetrahydrofuran results in isomerization of the olefin. When the concentration of molybdenum hexacarbonyl is greater than 0.05M less than 1 mole of the isomerized olefin is producedfor each mole of molybdenum hexacarbonyl. The efficiency of the isomerization decreases as the concentration of molybdenum hexacarbonyl is increased. Under the condition used, the isomerization was initially rapid, but stopped completely after approximately 10 minutes. Penerbit UKM 1977 Article PeerReviewed application/pdf en http://irep.iium.edu.my/30235/1/DR_NO_Sains_Malaysiana_1977.pdf Card, Roger J. and Omar, Muhammad Nor (1977) Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran. Sains Malaysiana, 6 (2). pp. 133-138. ISSN 0126-6039 |
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QD Chemistry Card, Roger J. Omar, Muhammad Nor Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran |
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The photolysis of 1-octene and molybdenum hexacarbonyl in tetrahydrofuran results in isomerization of the olefin. When the concentration of molybdenum hexacarbonyl is greater than 0.05M less than 1 mole of the isomerized olefin is producedfor each mole of molybdenum hexacarbonyl. The efficiency of the isomerization decreases as the concentration of molybdenum hexacarbonyl is increased. Under the condition used, the isomerization was initially rapid, but stopped completely after approximately 10 minutes. |
format |
Article |
author |
Card, Roger J. Omar, Muhammad Nor |
author_facet |
Card, Roger J. Omar, Muhammad Nor |
author_sort |
Card, Roger J. |
title |
Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran |
title_short |
Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran |
title_full |
Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran |
title_fullStr |
Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran |
title_full_unstemmed |
Photolysis of 1-Octene and Molybdenum Hexacarbonyl in Tetrahydrofuran |
title_sort |
photolysis of 1-octene and molybdenum hexacarbonyl in tetrahydrofuran |
publisher |
Penerbit UKM |
publishDate |
1977 |
url |
http://irep.iium.edu.my/30235/1/DR_NO_Sains_Malaysiana_1977.pdf http://irep.iium.edu.my/30235/ |
_version_ |
1646012400103587840 |
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13.15806 |