Possible origin of electronic effects in Rh(I)-catalyzed enantioselective hydrogenation
Reducing the electron density of ligands switches the regioselectivity of Rh(I)-catalyzed hydrometalation. A reversal of the sense of chiral induction was also observed when chiral ligands are electronically tuned in the same manner. The combined data provide an alternative rationale for the electro...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society
2009
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| Subjects: | |
| Online Access: | http://irep.iium.edu.my/10332/1/sw-2.pdf http://irep.iium.edu.my/10332/ http://pubs.acs.org/doi/abs/10.1021/ja903089f |
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