Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien

A new series of lanthanum dialkyldithiocarbamate complexes with 1,10-phenantroline were successfully synthesized using in situ methods. These complexes were characterized using elemental analysis, infrared, thermogravimetric analysis and conductivity. Microelemental analysis data were in agreement...

Full description

Saved in:
Bibliographic Details
Main Authors: Ibrahim Baba,, Indah Raya,, Bohari Mohd Yamin,
Format: Article
Language:English
Published: Universiti Kebangsaan Malaysia 2009
Online Access:http://journalarticle.ukm.my/59/1/
http://journalarticle.ukm.my/59/
http://www.ukm.my/~jsm/utama.html
Tags: Add Tag
No Tags, Be the first to tag this record!
id my-ukm.journal.59
record_format eprints
spelling my-ukm.journal.592016-12-14T06:26:17Z http://journalarticle.ukm.my/59/ Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien Ibrahim Baba, Indah Raya, Bohari Mohd Yamin, A new series of lanthanum dialkyldithiocarbamate complexes with 1,10-phenantroline were successfully synthesized using in situ methods. These complexes were characterized using elemental analysis, infrared, thermogravimetric analysis and conductivity. Microelemental analysis data were in agreement with the general formula La(S2CNR’R”)3phen (R’=ethyl, methyl; R”=butyl, heptyl, isopropyl, isobutyl, benzyl and cyclohexyl; phen = 1,10-phenantroline). Infrared spectra of complexes showed the thioureide ν(C-N) bands were in the region of 1450 - 1482 cm-1. The single ν(C-S) bands appeared in the region of 959 – 997 cm-1 and ν(C-H) bands in the region of 2918-2955 cm-1. The crystal structure of tris(N,Nethylbenzyldithiocarbamate)( 1,10-phenantroline)lantanum(III) adopts an orthorombic system (space group Pccn) with a distorted dodecahedron geometry with a = 19.865(5) Å , b = 42.803(10) Å, c = 10.657(3) Å, α = β = γ= 90o and Z = 9. Three dithiocarbamates and one phenanthroline ligands were coordinated to the central La atom in bidentate manner. Universiti Kebangsaan Malaysia 2009-04 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/59/1/ Ibrahim Baba, and Indah Raya, and Bohari Mohd Yamin, (2009) Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien. Sains Malaysiana, 38 (2). pp. 185-190. ISSN 0126-6039 http://www.ukm.my/~jsm/utama.html
institution Universiti Kebangsaan Malaysia
building Perpustakaan Tun Sri Lanang Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Kebangsaan Malaysia
content_source UKM Journal Article Repository
url_provider http://journalarticle.ukm.my/
language English
description A new series of lanthanum dialkyldithiocarbamate complexes with 1,10-phenantroline were successfully synthesized using in situ methods. These complexes were characterized using elemental analysis, infrared, thermogravimetric analysis and conductivity. Microelemental analysis data were in agreement with the general formula La(S2CNR’R”)3phen (R’=ethyl, methyl; R”=butyl, heptyl, isopropyl, isobutyl, benzyl and cyclohexyl; phen = 1,10-phenantroline). Infrared spectra of complexes showed the thioureide ν(C-N) bands were in the region of 1450 - 1482 cm-1. The single ν(C-S) bands appeared in the region of 959 – 997 cm-1 and ν(C-H) bands in the region of 2918-2955 cm-1. The crystal structure of tris(N,Nethylbenzyldithiocarbamate)( 1,10-phenantroline)lantanum(III) adopts an orthorombic system (space group Pccn) with a distorted dodecahedron geometry with a = 19.865(5) Å , b = 42.803(10) Å, c = 10.657(3) Å, α = β = γ= 90o and Z = 9. Three dithiocarbamates and one phenanthroline ligands were coordinated to the central La atom in bidentate manner.
format Article
author Ibrahim Baba,
Indah Raya,
Bohari Mohd Yamin,
spellingShingle Ibrahim Baba,
Indah Raya,
Bohari Mohd Yamin,
Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien
author_facet Ibrahim Baba,
Indah Raya,
Bohari Mohd Yamin,
author_sort Ibrahim Baba,
title Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien
title_short Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien
title_full Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien
title_fullStr Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien
title_full_unstemmed Synthesis and structural studies of lanthanum (III) dialkyldithiocarbamate, 1,10-phenantrolien
title_sort synthesis and structural studies of lanthanum (iii) dialkyldithiocarbamate, 1,10-phenantrolien
publisher Universiti Kebangsaan Malaysia
publishDate 2009
url http://journalarticle.ukm.my/59/1/
http://journalarticle.ukm.my/59/
http://www.ukm.my/~jsm/utama.html
_version_ 1643734601784360960
score 13.222552