Zirconium(IV)-BTC-based MOF modified with nickel as a catalyst for hydrogenation of citronellal

This study is designed to determine the effect of nickel (Ni) metal bearing on zirconium(IV) benzene 1,3,5-tricarboxylate based MOF, [Zr6 O4 (OH)4 (O2 C2 H3 )6 (BTC)2 ] (Zr-BTC) and its application as a catalyst in the citronellal hydrogenation. The synthesis of Zr-BTC was carried out un...

Full description

Saved in:
Bibliographic Details
Main Authors: Lestari, Witri Wahyu, Aqna, Arifti Nur Laily, Prihadiyono, Fauzan Ibnu, Putra, Riandy, Firdaus, Maulidan, Rosari, Venansia Avelia, Arrozi, Ubed Sonai Fahrudin, Kadja, Grandprix T.M.
Format: Article
Language:English
Published: Penerbit Universiti Kebangsaan Malaysia 2022
Online Access:http://journalarticle.ukm.my/20648/1/16.pdf
http://journalarticle.ukm.my/20648/
https://www.ukm.my/jsm/malay_journals/jilid51bil9_2022/KandunganJilid51Bil9_2022.html
Tags: Add Tag
No Tags, Be the first to tag this record!
id my-ukm.journal.20648
record_format eprints
spelling my-ukm.journal.206482022-12-06T09:23:58Z http://journalarticle.ukm.my/20648/ Zirconium(IV)-BTC-based MOF modified with nickel as a catalyst for hydrogenation of citronellal Lestari, Witri Wahyu Aqna, Arifti Nur Laily Prihadiyono, Fauzan Ibnu Putra, Riandy Firdaus, Maulidan Rosari, Venansia Avelia Arrozi, Ubed Sonai Fahrudin Kadja, Grandprix T.M. This study is designed to determine the effect of nickel (Ni) metal bearing on zirconium(IV) benzene 1,3,5-tricarboxylate based MOF, [Zr6 O4 (OH)4 (O2 C2 H3 )6 (BTC)2 ] (Zr-BTC) and its application as a catalyst in the citronellal hydrogenation. The synthesis of Zr-BTC was carried out under solvothermal condition, while the wet impregnation method was used to synthesize 2.5 wt.% Ni/Zr-BTC. The catalytic test of citronellal hydrogenation was performed in a batch reactor at 80 °C for 6 h with various hydrogen pressures. XRD characterization showed the suitability of the prominent peaks of Zr-BTC to the standard pattern, while Ni metal could not be detected clearly but was confirmed by EDX analysis. FTIR analysis showed a significant shift in the wavenumber from 1722 cm-1 to 1567 cm-1 indicating coordination of deprotonated ligands to the Zr4+ metal ions. Nickel loading reduced the surface area of Zr-BTC to 523 m2 /g and the pore volume to 0.11 cc/g according to the nitrogen sorption isotherm. The catalytic tests showed that 30% Ni loading enhanced the activity and selectivity of Zr-BTC in citronellal hydrogenation, resulting in 62.1% yield of isopulegol (for batch reactor) and 14.1% yield of citronellol (for hydrogen balloon). Penerbit Universiti Kebangsaan Malaysia 2022-09 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/20648/1/16.pdf Lestari, Witri Wahyu and Aqna, Arifti Nur Laily and Prihadiyono, Fauzan Ibnu and Putra, Riandy and Firdaus, Maulidan and Rosari, Venansia Avelia and Arrozi, Ubed Sonai Fahrudin and Kadja, Grandprix T.M. (2022) Zirconium(IV)-BTC-based MOF modified with nickel as a catalyst for hydrogenation of citronellal. Sains Malaysiana, 51 (9). pp. 2937-2954. ISSN 0126-6039 https://www.ukm.my/jsm/malay_journals/jilid51bil9_2022/KandunganJilid51Bil9_2022.html
institution Universiti Kebangsaan Malaysia
building Tun Sri Lanang Library
collection Institutional Repository
continent Asia
country Malaysia
content_provider Universiti Kebangsaan Malaysia
content_source UKM Journal Article Repository
url_provider http://journalarticle.ukm.my/
language English
description This study is designed to determine the effect of nickel (Ni) metal bearing on zirconium(IV) benzene 1,3,5-tricarboxylate based MOF, [Zr6 O4 (OH)4 (O2 C2 H3 )6 (BTC)2 ] (Zr-BTC) and its application as a catalyst in the citronellal hydrogenation. The synthesis of Zr-BTC was carried out under solvothermal condition, while the wet impregnation method was used to synthesize 2.5 wt.% Ni/Zr-BTC. The catalytic test of citronellal hydrogenation was performed in a batch reactor at 80 °C for 6 h with various hydrogen pressures. XRD characterization showed the suitability of the prominent peaks of Zr-BTC to the standard pattern, while Ni metal could not be detected clearly but was confirmed by EDX analysis. FTIR analysis showed a significant shift in the wavenumber from 1722 cm-1 to 1567 cm-1 indicating coordination of deprotonated ligands to the Zr4+ metal ions. Nickel loading reduced the surface area of Zr-BTC to 523 m2 /g and the pore volume to 0.11 cc/g according to the nitrogen sorption isotherm. The catalytic tests showed that 30% Ni loading enhanced the activity and selectivity of Zr-BTC in citronellal hydrogenation, resulting in 62.1% yield of isopulegol (for batch reactor) and 14.1% yield of citronellol (for hydrogen balloon).
format Article
author Lestari, Witri Wahyu
Aqna, Arifti Nur Laily
Prihadiyono, Fauzan Ibnu
Putra, Riandy
Firdaus, Maulidan
Rosari, Venansia Avelia
Arrozi, Ubed Sonai Fahrudin
Kadja, Grandprix T.M.
spellingShingle Lestari, Witri Wahyu
Aqna, Arifti Nur Laily
Prihadiyono, Fauzan Ibnu
Putra, Riandy
Firdaus, Maulidan
Rosari, Venansia Avelia
Arrozi, Ubed Sonai Fahrudin
Kadja, Grandprix T.M.
Zirconium(IV)-BTC-based MOF modified with nickel as a catalyst for hydrogenation of citronellal
author_facet Lestari, Witri Wahyu
Aqna, Arifti Nur Laily
Prihadiyono, Fauzan Ibnu
Putra, Riandy
Firdaus, Maulidan
Rosari, Venansia Avelia
Arrozi, Ubed Sonai Fahrudin
Kadja, Grandprix T.M.
author_sort Lestari, Witri Wahyu
title Zirconium(IV)-BTC-based MOF modified with nickel as a catalyst for hydrogenation of citronellal
title_short Zirconium(IV)-BTC-based MOF modified with nickel as a catalyst for hydrogenation of citronellal
title_full Zirconium(IV)-BTC-based MOF modified with nickel as a catalyst for hydrogenation of citronellal
title_fullStr Zirconium(IV)-BTC-based MOF modified with nickel as a catalyst for hydrogenation of citronellal
title_full_unstemmed Zirconium(IV)-BTC-based MOF modified with nickel as a catalyst for hydrogenation of citronellal
title_sort zirconium(iv)-btc-based mof modified with nickel as a catalyst for hydrogenation of citronellal
publisher Penerbit Universiti Kebangsaan Malaysia
publishDate 2022
url http://journalarticle.ukm.my/20648/1/16.pdf
http://journalarticle.ukm.my/20648/
https://www.ukm.my/jsm/malay_journals/jilid51bil9_2022/KandunganJilid51Bil9_2022.html
_version_ 1751537490082136064
score 13.222552