Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide
Tungsten oxides (WO3) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H2O2 in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation...
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Springer
2008
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| Online Access: | http://eprints.utm.my/7321/ http://dx.doi.org/10.1007/s10562-008-9727-7 |
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| author | Prasetyoko, Didik Fansuri, Hamzah Ramli, Zainab Endud, Salasiah Nur, Hadi |
| author_facet | Prasetyoko, Didik Fansuri, Hamzah Ramli, Zainab Endud, Salasiah Nur, Hadi |
| author_sort | Prasetyoko, Didik |
| building | UTM Library |
| collection | Institutional Repository |
| content_provider | Universiti Teknologi Malaysia |
| content_source | UTM Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | Tungsten oxides (WO3) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H2O2 in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation of epoxide. Diol as a site-product was also observed due to the acidic properties of the catalysts. |
| format | Article |
| id | my.utm.eprints-7321 |
| institution | Universiti Teknologi Malaysia |
| publishDate | 2008 |
| publisher | Springer |
| record_format | eprints |
| spelling | my.utm.eprints-73212011-04-22T02:20:02Z http://eprints.utm.my/7321/ Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide Prasetyoko, Didik Fansuri, Hamzah Ramli, Zainab Endud, Salasiah Nur, Hadi QD Chemistry Tungsten oxides (WO3) have been supported on the titanium silicalite (TS-1) by impregnation method. The solids have been tested for epoxidation of 1-octene with aqueous H2O2 in acetone as solvent. It was found that the presence of tungstate species in the catalysts enhanced the rate of the formation of epoxide. Diol as a site-product was also observed due to the acidic properties of the catalysts. Springer 2008 Article PeerReviewed Prasetyoko, Didik and Fansuri, Hamzah and Ramli, Zainab and Endud, Salasiah and Nur, Hadi (2008) Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide. Catalysis Letters . pp. 1-6. ISSN 1011-372X http://dx.doi.org/10.1007/s10562-008-9727-7 10.1007/s10562-008-9727-7 |
| spellingShingle | QD Chemistry Prasetyoko, Didik Fansuri, Hamzah Ramli, Zainab Endud, Salasiah Nur, Hadi Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide |
| title | Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide |
| title_full | Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide |
| title_fullStr | Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide |
| title_full_unstemmed | Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide |
| title_short | Tungsten oxides-containing Titanium Silicalite for liquid phase epoxidation of 1-octene with Aqueous Hydrogen Peroxide |
| title_sort | tungsten oxides-containing titanium silicalite for liquid phase epoxidation of 1-octene with aqueous hydrogen peroxide |
| topic | QD Chemistry |
| url | http://eprints.utm.my/7321/ http://dx.doi.org/10.1007/s10562-008-9727-7 |
| url_provider | http://eprints.utm.my/ |