Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction
In this paper, ZnO heterojunction with Ag2CO3/Ag2O mixed phase was synthesized by precipitation and phase transformation routes. The synthesized photocatalysts were characterized by X-ray diffraction (XRD), BET specific surface area, field emission scanning electron microscopy (FESEM), transmission...
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Elsevier
2018
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| Online Access: | http://eprints.uthm.edu.my/3336/1/AJ%202018%20%28343%29.pdf http://eprints.uthm.edu.my/3336/ https://doi.org/10.1016/j.jphotochem.2018.06.029 |
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| author | Rosman, Nurafiqah Wan Salleh, Wan Norharyati Ismail, Ahmad Fauzi Jaafar, Juhana Harun, Zawati Aziz, Farhana Mohamed, Mohamad Azuwa Ohtani, Bunsho Takashima, Mai |
| author_facet | Rosman, Nurafiqah Wan Salleh, Wan Norharyati Ismail, Ahmad Fauzi Jaafar, Juhana Harun, Zawati Aziz, Farhana Mohamed, Mohamad Azuwa Ohtani, Bunsho Takashima, Mai |
| author_sort | Rosman, Nurafiqah |
| building | UTHM Library |
| collection | Institutional Repository |
| content_provider | Universiti Tun Hussein Onn Malaysia |
| content_source | UTHM Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | In this paper, ZnO heterojunction with Ag2CO3/Ag2O mixed phase was synthesized by precipitation and phase transformation routes. The synthesized photocatalysts were characterized by X-ray diffraction (XRD), BET specific surface area, field emission scanning electron microscopy (FESEM), transmission electron microscopy along with energy-dispersive X-ray (TEM-EDX), Fourier transform infrared (FTIR), UV-Vis-NIR spectrophotometer to reveal their phase, morphology, purity, and optical properties. The photocatalytic activity of the obtained nanocomposites was measured by the degradation of phenol under visible light irradiation. The results demonstrated that, the heterojunction mixed phase of Ag2CO3/Ag2O over ZnO surfaces has major effect on establishing the performance of the phenol photodegradation process. It can be noted that the Ag2O crystal’s growth over Ag2CO3 heterojunction on ZnO lattice, effectively facilitate charge transfer and suppress recombination of photogenerated electrons and holes, leading to highest impact phenol degradation. The synthesized photocatalyst displayed excellent properties, showing a potential industrial application for the treatment of phenolic wastewater. |
| format | Article |
| id | my.uthm.eprints-3336 |
| institution | Universiti Tun Hussein Onn Malaysia |
| language | en |
| publishDate | 2018 |
| publisher | Elsevier |
| record_format | eprints |
| spelling | my.uthm.eprints-33362021-11-16T07:38:47Z http://eprints.uthm.edu.my/3336/ Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction Rosman, Nurafiqah Wan Salleh, Wan Norharyati Ismail, Ahmad Fauzi Jaafar, Juhana Harun, Zawati Aziz, Farhana Mohamed, Mohamad Azuwa Ohtani, Bunsho Takashima, Mai TA401-492 Materials of engineering and construction. Mechanics of materials In this paper, ZnO heterojunction with Ag2CO3/Ag2O mixed phase was synthesized by precipitation and phase transformation routes. The synthesized photocatalysts were characterized by X-ray diffraction (XRD), BET specific surface area, field emission scanning electron microscopy (FESEM), transmission electron microscopy along with energy-dispersive X-ray (TEM-EDX), Fourier transform infrared (FTIR), UV-Vis-NIR spectrophotometer to reveal their phase, morphology, purity, and optical properties. The photocatalytic activity of the obtained nanocomposites was measured by the degradation of phenol under visible light irradiation. The results demonstrated that, the heterojunction mixed phase of Ag2CO3/Ag2O over ZnO surfaces has major effect on establishing the performance of the phenol photodegradation process. It can be noted that the Ag2O crystal’s growth over Ag2CO3 heterojunction on ZnO lattice, effectively facilitate charge transfer and suppress recombination of photogenerated electrons and holes, leading to highest impact phenol degradation. The synthesized photocatalyst displayed excellent properties, showing a potential industrial application for the treatment of phenolic wastewater. Elsevier 2018 Article PeerReviewed text en http://eprints.uthm.edu.my/3336/1/AJ%202018%20%28343%29.pdf Rosman, Nurafiqah and Wan Salleh, Wan Norharyati and Ismail, Ahmad Fauzi and Jaafar, Juhana and Harun, Zawati and Aziz, Farhana and Mohamed, Mohamad Azuwa and Ohtani, Bunsho and Takashima, Mai (2018) Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction. Journal of Photochemistry and Photobiology A: Chemistry, 364 (18). pp. 602-612. ISSN 1010-6030 https://doi.org/10.1016/j.jphotochem.2018.06.029 |
| spellingShingle | TA401-492 Materials of engineering and construction. Mechanics of materials Rosman, Nurafiqah Wan Salleh, Wan Norharyati Ismail, Ahmad Fauzi Jaafar, Juhana Harun, Zawati Aziz, Farhana Mohamed, Mohamad Azuwa Ohtani, Bunsho Takashima, Mai Photocatalytic degradation of phenol over visible light active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction |
| title | Photocatalytic degradation of phenol over visible light
active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction |
| title_full | Photocatalytic degradation of phenol over visible light
active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction |
| title_fullStr | Photocatalytic degradation of phenol over visible light
active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction |
| title_full_unstemmed | Photocatalytic degradation of phenol over visible light
active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction |
| title_short | Photocatalytic degradation of phenol over visible light
active ZnO/Ag2CO3/Ag2O nanocomposites heterojunction |
| title_sort | photocatalytic degradation of phenol over visible light
active zno/ag2co3/ag2o nanocomposites heterojunction |
| topic | TA401-492 Materials of engineering and construction. Mechanics of materials |
| url | http://eprints.uthm.edu.my/3336/1/AJ%202018%20%28343%29.pdf http://eprints.uthm.edu.my/3336/ https://doi.org/10.1016/j.jphotochem.2018.06.029 |
| url_provider | http://eprints.uthm.edu.my/ |