Effect of aqueous media on photoelectrochemical water splitting performance of �-Fe2O3/LaFeO3:Cr tandem cell
A tandem cell that consists of an n-type (�-Fe2O3/hematite) photoanode and a p-type (LFO:Cr/chromium-doped lanthanum iron oxide) photocathode for solar water splitting has been demonstrated and studied for its photoelectrochemically. Under two-electrode system configurations, the PEC performance of...
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Springer Nature
2025
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| author | Aadenan A. Arzaee N.A. Rahman N.A.A. Noh M.F.M. Daud M.N.M. Mohamed N.A. Mustapha M. Ibrahim M.A. Ludin N.A. Teridi M.A.M. |
| author2 | 57208906799 |
| author_facet | 57208906799 Aadenan A. Arzaee N.A. Rahman N.A.A. Noh M.F.M. Daud M.N.M. Mohamed N.A. Mustapha M. Ibrahim M.A. Ludin N.A. Teridi M.A.M. |
| author_sort | Aadenan A. |
| building | UNITEN Library |
| collection | Institutional Repository |
| content_provider | Universiti Tenaga Nasional |
| content_source | UNITEN Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | A tandem cell that consists of an n-type (�-Fe2O3/hematite) photoanode and a p-type (LFO:Cr/chromium-doped lanthanum iron oxide) photocathode for solar water splitting has been demonstrated and studied for its photoelectrochemically. Under two-electrode system configurations, the PEC performance of �-Fe2O3 exhibited a good photoanodic response with the highest photocurrent density achieved was 0.0047�mA and 0.066�mA�cm?2 at 1.23�V (vs. LFO and LFO:Cr), respectively, as operated in 0.1�M KOH (pH 13) electrolyte. Furthermore, the tandem of (LFO and LFO:Cr) vs. �-Fe2O3 also presented a similar increase of photocurrent responses as operated in different aqueous media. At zero bias condition, the highest photocurrent constructed in a two-electrode system was 0.0022�mA�cm?2 for �-Fe2O3 vs. LFO:Cr, which increased by 0.0006�mA�cm?2 from �-Fe2O3 vs. LFO tandem cell in 0.1�M KOH electrolyte. As a result, the solar-to-hydrogen (STH) efficiency of 0.0026% was achieved under AM 1.5 G illumination. Graphical Abstract: (Figure presented.) ? The Author(s), under exclusive licence to The Materials Research Society 2023. |
| format | Article |
| id | my.uniten.dspace-36701 |
| institution | Universiti Tenaga Nasional |
| publishDate | 2025 |
| publisher | Springer Nature |
| record_format | dspace |
| spelling | my.uniten.dspace-367012025-03-03T15:44:01Z Effect of aqueous media on photoelectrochemical water splitting performance of �-Fe2O3/LaFeO3:Cr tandem cell Aadenan A. Arzaee N.A. Rahman N.A.A. Noh M.F.M. Daud M.N.M. Mohamed N.A. Mustapha M. Ibrahim M.A. Ludin N.A. Teridi M.A.M. 57208906799 57204034965 58773310000 57200419635 57217289318 57201821340 57210767098 55843508000 55385629400 12801271200 Chromium compounds Electrodes Electrolytes Hematite Photocurrents Photoelectrochemical cells Potassium hydroxide Solar power generation Aqueous media Hematite photoanode LaFeO3:cr Performance Photoelectrochemical water splitting Photoelectrochemicals Tandem cells Two-electrode systems Water splitting ?-fe2O3 Lanthanum compounds A tandem cell that consists of an n-type (�-Fe2O3/hematite) photoanode and a p-type (LFO:Cr/chromium-doped lanthanum iron oxide) photocathode for solar water splitting has been demonstrated and studied for its photoelectrochemically. Under two-electrode system configurations, the PEC performance of �-Fe2O3 exhibited a good photoanodic response with the highest photocurrent density achieved was 0.0047�mA and 0.066�mA�cm?2 at 1.23�V (vs. LFO and LFO:Cr), respectively, as operated in 0.1�M KOH (pH 13) electrolyte. Furthermore, the tandem of (LFO and LFO:Cr) vs. �-Fe2O3 also presented a similar increase of photocurrent responses as operated in different aqueous media. At zero bias condition, the highest photocurrent constructed in a two-electrode system was 0.0022�mA�cm?2 for �-Fe2O3 vs. LFO:Cr, which increased by 0.0006�mA�cm?2 from �-Fe2O3 vs. LFO tandem cell in 0.1�M KOH electrolyte. As a result, the solar-to-hydrogen (STH) efficiency of 0.0026% was achieved under AM 1.5 G illumination. Graphical Abstract: (Figure presented.) ? The Author(s), under exclusive licence to The Materials Research Society 2023. Final 2025-03-03T07:44:01Z 2025-03-03T07:44:01Z 2024 Article 10.1557/s43578-023-01262-9 2-s2.0-85180254459 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85180254459&doi=10.1557%2fs43578-023-01262-9&partnerID=40&md5=4c647a9a85de558d2e74ebf3615213fe https://irepository.uniten.edu.my/handle/123456789/36701 39 5 737 749 Springer Nature Scopus |
| spellingShingle | Chromium compounds Electrodes Electrolytes Hematite Photocurrents Photoelectrochemical cells Potassium hydroxide Solar power generation Aqueous media Hematite photoanode LaFeO3:cr Performance Photoelectrochemical water splitting Photoelectrochemicals Tandem cells Two-electrode systems Water splitting ?-fe2O3 Lanthanum compounds Aadenan A. Arzaee N.A. Rahman N.A.A. Noh M.F.M. Daud M.N.M. Mohamed N.A. Mustapha M. Ibrahim M.A. Ludin N.A. Teridi M.A.M. Effect of aqueous media on photoelectrochemical water splitting performance of �-Fe2O3/LaFeO3:Cr tandem cell |
| title | Effect of aqueous media on photoelectrochemical water splitting performance of �-Fe2O3/LaFeO3:Cr tandem cell |
| title_full | Effect of aqueous media on photoelectrochemical water splitting performance of �-Fe2O3/LaFeO3:Cr tandem cell |
| title_fullStr | Effect of aqueous media on photoelectrochemical water splitting performance of �-Fe2O3/LaFeO3:Cr tandem cell |
| title_full_unstemmed | Effect of aqueous media on photoelectrochemical water splitting performance of �-Fe2O3/LaFeO3:Cr tandem cell |
| title_short | Effect of aqueous media on photoelectrochemical water splitting performance of �-Fe2O3/LaFeO3:Cr tandem cell |
| title_sort | effect of aqueous media on photoelectrochemical water splitting performance of �-fe2o3/lafeo3:cr tandem cell |
| topic | Chromium compounds Electrodes Electrolytes Hematite Photocurrents Photoelectrochemical cells Potassium hydroxide Solar power generation Aqueous media Hematite photoanode LaFeO3:cr Performance Photoelectrochemical water splitting Photoelectrochemicals Tandem cells Two-electrode systems Water splitting ?-fe2O3 Lanthanum compounds |
| url_provider | http://dspace.uniten.edu.my/ |