Preparation and characterization of PMMA-MG49-LiClO4 solid polymeric electrolyte
The potential of hybrid polymer 49% poly(methyl methacrylate)-grafted natural rubber (MG49) and poly(methyl methacrylate) (PMMA) as a polymer host in solid polymer electrolyte film for rechargeable battery systems has been investigated. The hybrid films were prepared by the solution casting techniqu...
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2023
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| author | Su'Ait M.S. Ahmad A. Hamzah H. Rahman M.Y.A. |
| author2 | 57223117728 |
| author_facet | 57223117728 Su'Ait M.S. Ahmad A. Hamzah H. Rahman M.Y.A. |
| author_sort | Su'Ait M.S. |
| building | UNITEN Library |
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| content_provider | Universiti Tenaga Nasional |
| content_source | UNITEN Institutional Repository |
| continent | Asia |
| country | Malaysia |
| description | The potential of hybrid polymer 49% poly(methyl methacrylate)-grafted natural rubber (MG49) and poly(methyl methacrylate) (PMMA) as a polymer host in solid polymer electrolyte film for rechargeable battery systems has been investigated. The hybrid films were prepared by the solution casting technique. The ionic conductivity was investigated by alternating current electrochemical impedance spectroscopy. The highest conductivity was 1.47 � 10 -8 S cm-1 at 20 wt% of LiClO4. The observation on structural studies performed by x-ray diffraction showed that the crystallinity phase is reduced at the highest conductivity. Fourier transform infrared spectroscopy analysis showed that the interaction between lithium ion and oxygen atoms occurred at carbonyl (C=O) and ether (C-O-C) groups. � 2009 IOP Publishing Ltd. |
| format | Article |
| id | my.uniten.dspace-30923 |
| institution | Universiti Tenaga Nasional |
| publishDate | 2023 |
| record_format | dspace |
| spelling | my.uniten.dspace-309232023-12-29T15:55:59Z Preparation and characterization of PMMA-MG49-LiClO4 solid polymeric electrolyte Su'Ait M.S. Ahmad A. Hamzah H. Rahman M.Y.A. 57223117728 16306307100 6602504994 55347217400 Electrochemical impedance spectroscopy Electrolytes Esters Ethers Fourier transform infrared spectroscopy Polymers X ray diffraction Alternating current Crystallinities Hybrid film Hybrid polymers Lithium ions Oxygen atom Solid polymer electrolyte films Solid polymeric electrolytes Solution-casting technique Structural studies Film preparation The potential of hybrid polymer 49% poly(methyl methacrylate)-grafted natural rubber (MG49) and poly(methyl methacrylate) (PMMA) as a polymer host in solid polymer electrolyte film for rechargeable battery systems has been investigated. The hybrid films were prepared by the solution casting technique. The ionic conductivity was investigated by alternating current electrochemical impedance spectroscopy. The highest conductivity was 1.47 � 10 -8 S cm-1 at 20 wt% of LiClO4. The observation on structural studies performed by x-ray diffraction showed that the crystallinity phase is reduced at the highest conductivity. Fourier transform infrared spectroscopy analysis showed that the interaction between lithium ion and oxygen atoms occurred at carbonyl (C=O) and ether (C-O-C) groups. � 2009 IOP Publishing Ltd. Final 2023-12-29T07:55:59Z 2023-12-29T07:55:59Z 2009 Article 10.1088/0022-3727/42/5/055410 2-s2.0-77649169359 https://www.scopus.com/inward/record.uri?eid=2-s2.0-77649169359&doi=10.1088%2f0022-3727%2f42%2f5%2f055410&partnerID=40&md5=021cb066af3827464522655802414d70 https://irepository.uniten.edu.my/handle/123456789/30923 42 5 55410 Scopus |
| spellingShingle | Electrochemical impedance spectroscopy Electrolytes Esters Ethers Fourier transform infrared spectroscopy Polymers X ray diffraction Alternating current Crystallinities Hybrid film Hybrid polymers Lithium ions Oxygen atom Solid polymer electrolyte films Solid polymeric electrolytes Solution-casting technique Structural studies Film preparation Su'Ait M.S. Ahmad A. Hamzah H. Rahman M.Y.A. Preparation and characterization of PMMA-MG49-LiClO4 solid polymeric electrolyte |
| title | Preparation and characterization of PMMA-MG49-LiClO4 solid polymeric electrolyte |
| title_full | Preparation and characterization of PMMA-MG49-LiClO4 solid polymeric electrolyte |
| title_fullStr | Preparation and characterization of PMMA-MG49-LiClO4 solid polymeric electrolyte |
| title_full_unstemmed | Preparation and characterization of PMMA-MG49-LiClO4 solid polymeric electrolyte |
| title_short | Preparation and characterization of PMMA-MG49-LiClO4 solid polymeric electrolyte |
| title_sort | preparation and characterization of pmma-mg49-liclo4 solid polymeric electrolyte |
| topic | Electrochemical impedance spectroscopy Electrolytes Esters Ethers Fourier transform infrared spectroscopy Polymers X ray diffraction Alternating current Crystallinities Hybrid film Hybrid polymers Lithium ions Oxygen atom Solid polymer electrolyte films Solid polymeric electrolytes Solution-casting technique Structural studies Film preparation |
| url_provider | http://dspace.uniten.edu.my/ |