Thermogravimetric kinetic analysis of in-situ catalytic pyrolysis of palm oil wastes with the presence of palm oil wastes ash catalyst

The thermal degradation and kinetic analysis for oil palm frond (OPF) and oil palm trunk (OPT) with its ashes were investigated using thermogravimetric approach (TGA). OPF ash, OPT ash and its mixtures are used as a natural source of catalysts in the pyrolytic conversion of the palm oil wastes to bi...

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Main Authors: S W, Hii, B L F, Chin, Chung Loong, Yiin, F R S, Majing, Z A, Jawad, H Y, Lim, S, Yusup, M N, Acda, P, Unrean, E, Rianawati
Format: Proceeding
Language:en
Published: 2021
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Online Access:http://ir.unimas.my/id/eprint/36544/1/thermogravimetric1.pdf
http://ir.unimas.my/id/eprint/36544/
https://iopscience.iop.org/article/10.1088/1757-899X/1195/1/012010
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author S W, Hii
B L F, Chin
Chung Loong, Yiin
F R S, Majing
Z A, Jawad
H Y, Lim
S, Yusup
M N, Acda
P, Unrean
E, Rianawati
author_facet S W, Hii
B L F, Chin
Chung Loong, Yiin
F R S, Majing
Z A, Jawad
H Y, Lim
S, Yusup
M N, Acda
P, Unrean
E, Rianawati
author_sort S W, Hii
building Centre for Academic Information Services (CAIS)
collection Institutional Repository
content_provider Universiti Malaysia Sarawak
content_source UNIMAS Institutional Repository
continent Asia
country Malaysia
description The thermal degradation and kinetic analysis for oil palm frond (OPF) and oil palm trunk (OPT) with its ashes were investigated using thermogravimetric approach (TGA). OPF ash, OPT ash and its mixtures are used as a natural source of catalysts in the pyrolytic conversion of the palm oil wastes to bioenergy. The TGA experiments were conducted in a range of heating rates of 10-100 K/min from the temperature of 323 K to 1173 K. Coats-Redfern model is applied in this study to evaluate the activation energy (EA) and pre-exponential factor (A). The average EA values ranged 24.27-32.36 kJ.mol−1 and 41.42-46.10 kJ.mol−1 for pyrolysis of OPF and OPT respectively. Meanwhile, the average EA values ranged 24.27-31.06 kJ.mol−1 and 31.77-43.45 kJ.mol−1 for catalytic pyrolysis of OPF and OPT respectively.
format Proceeding
id my.unimas.ir-36544
institution Universiti Malaysia Sarawak
language en
publishDate 2021
record_format eprints
spelling my.unimas.ir-365442021-11-03T01:49:32Z http://ir.unimas.my/id/eprint/36544/ Thermogravimetric kinetic analysis of in-situ catalytic pyrolysis of palm oil wastes with the presence of palm oil wastes ash catalyst S W, Hii B L F, Chin Chung Loong, Yiin F R S, Majing Z A, Jawad H Y, Lim S, Yusup M N, Acda P, Unrean E, Rianawati TA Engineering (General). Civil engineering (General) TP Chemical technology The thermal degradation and kinetic analysis for oil palm frond (OPF) and oil palm trunk (OPT) with its ashes were investigated using thermogravimetric approach (TGA). OPF ash, OPT ash and its mixtures are used as a natural source of catalysts in the pyrolytic conversion of the palm oil wastes to bioenergy. The TGA experiments were conducted in a range of heating rates of 10-100 K/min from the temperature of 323 K to 1173 K. Coats-Redfern model is applied in this study to evaluate the activation energy (EA) and pre-exponential factor (A). The average EA values ranged 24.27-32.36 kJ.mol−1 and 41.42-46.10 kJ.mol−1 for pyrolysis of OPF and OPT respectively. Meanwhile, the average EA values ranged 24.27-31.06 kJ.mol−1 and 31.77-43.45 kJ.mol−1 for catalytic pyrolysis of OPF and OPT respectively. 2021 Proceeding PeerReviewed text en http://ir.unimas.my/id/eprint/36544/1/thermogravimetric1.pdf S W, Hii and B L F, Chin and Chung Loong, Yiin and F R S, Majing and Z A, Jawad and H Y, Lim and S, Yusup and M N, Acda and P, Unrean and E, Rianawati (2021) Thermogravimetric kinetic analysis of in-situ catalytic pyrolysis of palm oil wastes with the presence of palm oil wastes ash catalyst. In: 32nd Symposium of Malaysian Chemical Engineers (SOMChE2021), 15th-16th July 2021, Kuching, Sarawak. https://iopscience.iop.org/article/10.1088/1757-899X/1195/1/012010
spellingShingle TA Engineering (General). Civil engineering (General)
TP Chemical technology
S W, Hii
B L F, Chin
Chung Loong, Yiin
F R S, Majing
Z A, Jawad
H Y, Lim
S, Yusup
M N, Acda
P, Unrean
E, Rianawati
Thermogravimetric kinetic analysis of in-situ catalytic pyrolysis of palm oil wastes with the presence of palm oil wastes ash catalyst
title Thermogravimetric kinetic analysis of in-situ catalytic pyrolysis of palm oil wastes with the presence of palm oil wastes ash catalyst
title_full Thermogravimetric kinetic analysis of in-situ catalytic pyrolysis of palm oil wastes with the presence of palm oil wastes ash catalyst
title_fullStr Thermogravimetric kinetic analysis of in-situ catalytic pyrolysis of palm oil wastes with the presence of palm oil wastes ash catalyst
title_full_unstemmed Thermogravimetric kinetic analysis of in-situ catalytic pyrolysis of palm oil wastes with the presence of palm oil wastes ash catalyst
title_short Thermogravimetric kinetic analysis of in-situ catalytic pyrolysis of palm oil wastes with the presence of palm oil wastes ash catalyst
title_sort thermogravimetric kinetic analysis of in-situ catalytic pyrolysis of palm oil wastes with the presence of palm oil wastes ash catalyst
topic TA Engineering (General). Civil engineering (General)
TP Chemical technology
url http://ir.unimas.my/id/eprint/36544/1/thermogravimetric1.pdf
http://ir.unimas.my/id/eprint/36544/
https://iopscience.iop.org/article/10.1088/1757-899X/1195/1/012010
url_provider http://ir.unimas.my/