A novel lightweight cement composite incorporating micro-sized silica aerogel / Syed Nasir Shah

Lightweight cement composite (LCC) has gained more interest and is increasingly explored by researchers due to its many advantageous properties. Silica aerogel (SA), a synthetic ultralightweight material with a nano-porous structure and remarkable insulation properties, makes it a potential optio...

Full description

Saved in:
Bibliographic Details
Main Author: Syed Nasir , Shah
Format: Thesis
Published: 2022
Subjects:
Online Access:http://studentsrepo.um.edu.my/15522/1/Syed_Nasir_Shah.pdf
http://studentsrepo.um.edu.my/15522/2/Syed_Nasir_Shah.pdf
http://studentsrepo.um.edu.my/15522/
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1831436648180613120
author Syed Nasir , Shah
author_facet Syed Nasir , Shah
author_sort Syed Nasir , Shah
building UM Library
collection Institutional Repository
content_provider Universiti Malaya
content_source UM Student Repository
continent Asia
country Malaysia
description Lightweight cement composite (LCC) has gained more interest and is increasingly explored by researchers due to its many advantageous properties. Silica aerogel (SA), a synthetic ultralightweight material with a nano-porous structure and remarkable insulation properties, makes it a potential option to be incorporated in LCC. LCC incorporating SA (SA-LCC) would be an ideal insulating building material and could promote energy efficiency in buildings since the building sector consumes about 30-40% of global energy consumption. However, there are some challenges when it comes to incorporating SA into LCC. One of the difficulties is mixing SA with cement composite due to its ultra-lightweight and hydrophobic nature. Thus, this research aims to develop a chemical treatment for SA to ease its mixing and assess the influence of micro-sized SA on the properties of LCC. Therefore, a detailed study was conducted on both untreated and treated SA-LCC. The study was divided into 3 phases; where phase 1 focuses on developing chemical treatment for SA, characterizing untreated and treated SA, and evaluating the effect of different content of untreated/treated SA (20-80% of sand replacement) on the basic properties of LCC. The results of phase 1 revealed that the treated SA became temporarily hydrophilic and eased the mixing. In addition, the chemical treatment did not affect the pore structure, particle size distribution, chemical bonds, and crystallographic structure of SA. A significant reduction in the oven-dry density (up to 50%) and compressive strength (up to 80%) of SA-LCC was observed, while the porosity was increased (up to 260%). Phase 2 emphasizes the insulating properties, dimensional stability, durability performance, and microstructure characteristics of SA-LCC. Despite the increase in water absorption (140/290%) and decrease in water resistance (11/19%), the increase in porosity of LCC due to incorporation of untreated/treated SA improved the insulating properties. The noise reduction coefficient (NRC) improved up to 15%, whereas the thermal conductivity was improved up to 80%. Despite the beneficial insulating properties, the limitations of the SA-LCC include the higher shrinkage (10 times) and lower resistance to elevated temperatures, in addition to increased water absorption. Nevertheless, in overall, LCC with a low oven-dry density of about 1190 kg/m3 and adequate compressive strength (6.38 MPa) can be produced by incorporating treated SA, which has a low thermal conductivity (0.220 W/m.K) and good NRC (0.261). Therefore, in phase 3, in view of the observed limitations of the SA-LCC, a scaled lightweight sandwich wall panel (SWP) was introduced, which utilized calcium silicate board (CSB) as the skin. This is intended for wall application to suit the benefits of the SA-LCC. The practical application of treated SA-LCC as core for SWP shows that non-load bearing SWP can be produced with treated SA-LCC and 6 mm CSB as the skin with unit weight, compressive, and flexural strength of 1570 kg/m3, 2.4 MPa, and 4.7 MPa, respectively. The SWP also has good impact load resistance (70 J) and direct flame resistance. Furthermore, the SWP has satisfactory insulating properties with NRC and thermal conductivity of 0.259 and 0.561 W/m.K, respectively.
format Thesis
id my.um.stud-15522
institution Universiti Malaya
publishDate 2022
record_format eprints
spelling my.um.stud-155222025-02-09T20:43:59Z A novel lightweight cement composite incorporating micro-sized silica aerogel / Syed Nasir Shah Syed Nasir , Shah TA Engineering (General). Civil engineering (General) Lightweight cement composite (LCC) has gained more interest and is increasingly explored by researchers due to its many advantageous properties. Silica aerogel (SA), a synthetic ultralightweight material with a nano-porous structure and remarkable insulation properties, makes it a potential option to be incorporated in LCC. LCC incorporating SA (SA-LCC) would be an ideal insulating building material and could promote energy efficiency in buildings since the building sector consumes about 30-40% of global energy consumption. However, there are some challenges when it comes to incorporating SA into LCC. One of the difficulties is mixing SA with cement composite due to its ultra-lightweight and hydrophobic nature. Thus, this research aims to develop a chemical treatment for SA to ease its mixing and assess the influence of micro-sized SA on the properties of LCC. Therefore, a detailed study was conducted on both untreated and treated SA-LCC. The study was divided into 3 phases; where phase 1 focuses on developing chemical treatment for SA, characterizing untreated and treated SA, and evaluating the effect of different content of untreated/treated SA (20-80% of sand replacement) on the basic properties of LCC. The results of phase 1 revealed that the treated SA became temporarily hydrophilic and eased the mixing. In addition, the chemical treatment did not affect the pore structure, particle size distribution, chemical bonds, and crystallographic structure of SA. A significant reduction in the oven-dry density (up to 50%) and compressive strength (up to 80%) of SA-LCC was observed, while the porosity was increased (up to 260%). Phase 2 emphasizes the insulating properties, dimensional stability, durability performance, and microstructure characteristics of SA-LCC. Despite the increase in water absorption (140/290%) and decrease in water resistance (11/19%), the increase in porosity of LCC due to incorporation of untreated/treated SA improved the insulating properties. The noise reduction coefficient (NRC) improved up to 15%, whereas the thermal conductivity was improved up to 80%. Despite the beneficial insulating properties, the limitations of the SA-LCC include the higher shrinkage (10 times) and lower resistance to elevated temperatures, in addition to increased water absorption. Nevertheless, in overall, LCC with a low oven-dry density of about 1190 kg/m3 and adequate compressive strength (6.38 MPa) can be produced by incorporating treated SA, which has a low thermal conductivity (0.220 W/m.K) and good NRC (0.261). Therefore, in phase 3, in view of the observed limitations of the SA-LCC, a scaled lightweight sandwich wall panel (SWP) was introduced, which utilized calcium silicate board (CSB) as the skin. This is intended for wall application to suit the benefits of the SA-LCC. The practical application of treated SA-LCC as core for SWP shows that non-load bearing SWP can be produced with treated SA-LCC and 6 mm CSB as the skin with unit weight, compressive, and flexural strength of 1570 kg/m3, 2.4 MPa, and 4.7 MPa, respectively. The SWP also has good impact load resistance (70 J) and direct flame resistance. Furthermore, the SWP has satisfactory insulating properties with NRC and thermal conductivity of 0.259 and 0.561 W/m.K, respectively. 2022-05 Thesis NonPeerReviewed application/pdf http://studentsrepo.um.edu.my/15522/1/Syed_Nasir_Shah.pdf application/pdf http://studentsrepo.um.edu.my/15522/2/Syed_Nasir_Shah.pdf Syed Nasir , Shah (2022) A novel lightweight cement composite incorporating micro-sized silica aerogel / Syed Nasir Shah. PhD thesis, Universiti Malaya. http://studentsrepo.um.edu.my/15522/
spellingShingle TA Engineering (General). Civil engineering (General)
Syed Nasir , Shah
A novel lightweight cement composite incorporating micro-sized silica aerogel / Syed Nasir Shah
title A novel lightweight cement composite incorporating micro-sized silica aerogel / Syed Nasir Shah
title_full A novel lightweight cement composite incorporating micro-sized silica aerogel / Syed Nasir Shah
title_fullStr A novel lightweight cement composite incorporating micro-sized silica aerogel / Syed Nasir Shah
title_full_unstemmed A novel lightweight cement composite incorporating micro-sized silica aerogel / Syed Nasir Shah
title_short A novel lightweight cement composite incorporating micro-sized silica aerogel / Syed Nasir Shah
title_sort novel lightweight cement composite incorporating micro-sized silica aerogel / syed nasir shah
topic TA Engineering (General). Civil engineering (General)
url http://studentsrepo.um.edu.my/15522/1/Syed_Nasir_Shah.pdf
http://studentsrepo.um.edu.my/15522/2/Syed_Nasir_Shah.pdf
http://studentsrepo.um.edu.my/15522/
url_provider http://studentsrepo.um.edu.my/