A highly active Zn(salphen) catalyst for production of organic carbonates in a green CO2 medium
Zn(salphen), in combination with Bu4NI, was studied as a binary catalyst system for CO2-fixation in the context of organic carbonate formation. The catalytic potential of this binary catalyst system was considerably improved by working in a solvent-free, CO2-rich environment, thereby increasing the...
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Royal Society of Chemistry
2012
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Online Access: | http://discol.umk.edu.my/id/eprint/7525/1/A%20highly%20active%20Zn%28salphen%29%20catalyst%20for%20production%20of%20organic%20carbonates.pdf http://discol.umk.edu.my/id/eprint/7525/ http://dx.doi.org/10.1039/C2CY20171B |
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my.umk.eprints.75252022-05-23T10:06:41Z http://discol.umk.edu.my/id/eprint/7525/ A highly active Zn(salphen) catalyst for production of organic carbonates in a green CO2 medium Taherimehr, Masoumeh Decortes, Antonello Al-Amsyar, Syed Muhammad Lueangchaichaweng, Warunee Whiteoak, Christopher J. Escudero-Adán, Eduardo C. Kleij, Arjan W. Pescarmona, Paolo P. QD Chemistry Zn(salphen), in combination with Bu4NI, was studied as a binary catalyst system for CO2-fixation in the context of organic carbonate formation. The catalytic potential of this binary catalyst system was considerably improved by working in a solvent-free, CO2-rich environment, thereby increasing the overall contact between the reagents and catalyst. Under these green conditions, excellent conversion and selectivity towards the cyclic carbonate product were obtained with epoxides that are generally less prone to undergo cycloaddition with carbon dioxide. The effect of the reaction conditions and the type of co-catalyst employed together with Zn(salphen) were systematically investigated and optimised. Royal Society of Chemistry 2012-04-18 Indexed Article PeerReviewed text en http://discol.umk.edu.my/id/eprint/7525/1/A%20highly%20active%20Zn%28salphen%29%20catalyst%20for%20production%20of%20organic%20carbonates.pdf Taherimehr, Masoumeh and Decortes, Antonello and Al-Amsyar, Syed Muhammad and Lueangchaichaweng, Warunee and Whiteoak, Christopher J. and Escudero-Adán, Eduardo C. and Kleij, Arjan W. and Pescarmona, Paolo P. (2012) A highly active Zn(salphen) catalyst for production of organic carbonates in a green CO2 medium. Catalysis Science & Technology, 2 (11). p. 2231. ISSN 2044-4753 http://dx.doi.org/10.1039/C2CY20171B doi:10.1039/C2CY20171B doi:10.1039/C2CY20171B |
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QD Chemistry Taherimehr, Masoumeh Decortes, Antonello Al-Amsyar, Syed Muhammad Lueangchaichaweng, Warunee Whiteoak, Christopher J. Escudero-Adán, Eduardo C. Kleij, Arjan W. Pescarmona, Paolo P. A highly active Zn(salphen) catalyst for production of organic carbonates in a green CO2 medium |
description |
Zn(salphen), in combination with Bu4NI, was studied as a binary catalyst system for CO2-fixation
in the context of organic carbonate formation. The catalytic potential of this binary catalyst
system was considerably improved by working in a solvent-free, CO2-rich environment, thereby
increasing the overall contact between the reagents and catalyst. Under these green conditions,
excellent conversion and selectivity towards the cyclic carbonate product were obtained with
epoxides that are generally less prone to undergo cycloaddition with carbon dioxide. The effect of
the reaction conditions and the type of co-catalyst employed together with Zn(salphen) were
systematically investigated and optimised. |
format |
Indexed Article |
author |
Taherimehr, Masoumeh Decortes, Antonello Al-Amsyar, Syed Muhammad Lueangchaichaweng, Warunee Whiteoak, Christopher J. Escudero-Adán, Eduardo C. Kleij, Arjan W. Pescarmona, Paolo P. |
author_facet |
Taherimehr, Masoumeh Decortes, Antonello Al-Amsyar, Syed Muhammad Lueangchaichaweng, Warunee Whiteoak, Christopher J. Escudero-Adán, Eduardo C. Kleij, Arjan W. Pescarmona, Paolo P. |
author_sort |
Taherimehr, Masoumeh |
title |
A highly active Zn(salphen) catalyst for production of organic carbonates in a green CO2 medium |
title_short |
A highly active Zn(salphen) catalyst for production of organic carbonates in a green CO2 medium |
title_full |
A highly active Zn(salphen) catalyst for production of organic carbonates in a green CO2 medium |
title_fullStr |
A highly active Zn(salphen) catalyst for production of organic carbonates in a green CO2 medium |
title_full_unstemmed |
A highly active Zn(salphen) catalyst for production of organic carbonates in a green CO2 medium |
title_sort |
highly active zn(salphen) catalyst for production of organic carbonates in a green co2 medium |
publisher |
Royal Society of Chemistry |
publishDate |
2012 |
url |
http://discol.umk.edu.my/id/eprint/7525/1/A%20highly%20active%20Zn%28salphen%29%20catalyst%20for%20production%20of%20organic%20carbonates.pdf http://discol.umk.edu.my/id/eprint/7525/ http://dx.doi.org/10.1039/C2CY20171B |
_version_ |
1763303853910917120 |
score |
13.1944895 |